Remediation of Surface Water Contaminated with Domestic Purpose Kerosene Using Fenton’s Oxidation
D. Y. Shinggu *
Department of Chemistry, Nigerian Army University Biu, Borno State, Nigeria.
J. H. Kanus
Department of Chemistry, Nigerian Army University Biu, Borno State, Nigeria.
W. O. Medjor
Department of Chemistry, Taraba State University, Jalingo, Taraba State, Nigeria.
*Author to whom correspondence should be addressed.
Abstract
The remediation of surface water contaminated with domestic purpose kerosene (DPK) using Fenton’s oxidation was investigated at ambient temperature for effectiveness at optimum conditions established. Results obtained from optimization studies for the Fenton’s oxidation employed for the study were 250000 mg/L H2O2 and 300 mg/L FeSO4 at ambient temperature with pH of samples adjusted to 3.0. At the end of the chemical remediation, the Fenton’s oxidation was found to be rapid with the reaction being exothermic and followed second order kinetics. About 44.4% of the total petroleum hydrocarbon (TPH) as kerosene removal efficiency was achieved after 90 minutes. The reaction also followed a pseudo-first order kinetics with the rate constant of 3x102 mol-1cm3min-1.
Keywords: Total Petroleum Hydrocarbon (TPH), contaminated surface water, chemical oxidation, Fenton’s oxidation.