Remediation of Surface Water Contaminated with Domestic Purpose Kerosene Using Fenton’s Oxidation
Chemical Science International Journal,
The remediation of surface water contaminated with domestic purpose kerosene (DPK) using Fenton’s oxidation was investigated at ambient temperature for effectiveness at optimum conditions established. Results obtained from optimization studies for the Fenton’s oxidation employed for the study were 250000 mg/L H2O2 and 300 mg/L FeSO4 at ambient temperature with pH of samples adjusted to 3.0. At the end of the chemical remediation, the Fenton’s oxidation was found to be rapid with the reaction being exothermic and followed second order kinetics. About 44.4% of the total petroleum hydrocarbon (TPH) as kerosene removal efficiency was achieved after 90 minutes. The reaction also followed a pseudo-first order kinetics with the rate constant of 3x102 mol-1cm3min-1.
- Total Petroleum Hydrocarbon (TPH)
- contaminated surface water
- chemical oxidation
- Fenton’s oxidation.
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Wang Z, Fingas M, Blenkinsopp S, Sergy G, Landriault M. et al. Comparison of oil composition changes due to biode-gradation and physical weathering in different soils. J. Chromatography. A., 1998;809:89-107.
Jain PK, Gupta VK, Gaur RK, Lowry M, Jaroli DP, Chauhan UK. Bioremediation of petroleum oil contaminated soil and water. Research Journal of Environmental Toxicology. 2011;5:1-26.
Paine R, Ruesink J, Sun A, Soulanille E, Wonham M, et al. Trouble on oiled waters: Lessons from the Exxon Valdes oil spill. Annu. Rev. Ecol. Syst. 1996;27:197-235.
Albaiges J, Morales-Nin B, Vilas F. The prestige oil spill: A scientific response. Mar. Pollut. Bull. 2006;53:205-207.
Whitfield J. How to clean a beach. Nature. 2003;422:464-466.
Wells O. Oil and sea birds- the imperative for preventing and reducing the continued illegal oiling of the seas by ships. Mar. Pollut. Bull. 2001;42:251-252.
Edewor TL, Adelewo OO, Afolabi TJ. Preliminary studies into the biological activities of a broad spectrum disinfectant formulated from used engine oil. Poll. Res. 2004;234:581-586.
HELMCOM. The Baltic marine environment 1999-2002. Baltic Sea Environment Proceedings, 87, Helsinki Commission. Baltic Marine Environment Protection Commission; 2003.
EPA. Understanding oil spills and oil spills response. Environmental Protection Agency, Washington Dc, USA; 1999.
Snape I, Riddle MJ, Stark JS, Cole CM, King CK, Duquesne S, Gore DB. Manage-ment and remediation of contaminated sites at Casey station. Antarctica Poll and Record. 2001;37:199-214.
Boehm PD, Douglas GS, Brown JS. Advanced chemical finger print for oil spill identification and natural resources damage assessments. Proceedings of the oil spill conference, (OSC95), API, Washington Dc. 1995;373-379.
Whittaker MS, Pollard TT, Risden G. The fate of heavy oil Wastes in soil microcosms H: A performance assessment of source correlation indices. Sci. Total Environ. 1999;226:23-34.
Medjor WO, Egharevba F, Akpoveta VO, Ize-Iyamu OK, Jatto EO. Remediation of crude-oil contaminated groundwater by Fenton-Oxidative method. International Journal of Environmental Sciences. 2012; 2(3):1398-1407,
EPA. Kinetics of Fenton reagent on contaminant of common concern; 2000.
Pignatello JJ, Oliveros E, Mackay A. Advanced oxidation processes for organic contaminant destruction based on the lenton reaction and related chemistry. Crit. Rev. Env. Sci. Technol. 2006;36:1-84.
Sylvia A. Remediation of petroleum hydro-carbons contaminated soil by fenton’s oxidation. Journal of Environmental Science and Public Health. 2018;2:168-178.
Bishop DF, et al. Hydrogen peroxide catalytic oxidation of refractory organics in municipal waste waters. In Ind. Eng. Chem., Process Design & Development. 1968;7:1110-117.
Bautista P, Mohedano AF, Casas JA, Zazo JA, Rodriguez JJ. An overview of the application of Fenton oxidation to industrial waste water treatment. J. Chem. Technol. Biotechnol. 2008;83:1323-1338.
Medjor, et al. Optimization, kinetics, physicochemical and ecotoxicity studies of fenton oxidative remediation of hydro-carbons contaminated groundwater, Egypt. J. Petrol. 2017.
Peroxide US. Fenton's reagent general chemistry, Hydrogen peroxide; 2013.
(Accessed November, 2018)
Huang CP, Dong C, Tang Z. Advanced chemical oxidation: its present role and potential future hazard. Waste Manage-ment. Lingering lessons of Exxon Valdez oil spill. 1993;13:361-377.
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